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Record W1984881795 · doi:10.1002/adfm.200304358

Holographic Recording in a Photoactive Elastomer

2003· article· en· W1984881795 on OpenAlexaff
Yue Zhao, Shuying Bai, K. Asatryan, Tigran Galstian

Bibliographic record

VenueAdvanced Functional Materials · 2003
Typearticle
Languageen
FieldMaterials Science
TopicLiquid Crystal Research Advancements
Canadian institutionsUniversité LavalOptech (Canada)Université de Sherbrooke
Fundersnot available
KeywordsAzobenzeneMaterials sciencePhotoisomerizationElastomerGratingHolographyPolybutadienePolymerDeformation (meteorology)Phase (matter)CopolymerSide chainComposite materialPhotochemistryOptoelectronicsOpticsOrganic chemistryIsomerization

Abstract

fetched live from OpenAlex

Abstract This work explores the use of photoactive elastomers as elastic holographic materials. Holographic gratings were recorded on stretched films of an azobenzene elastomer, which is composed of a side‐chain liquid‐crystalline polymer with azobenzene mesogens, grafted to the rubbery polybutadiene block of a styrene–butadiene–styrene (SBS) triblock copolymer. The grating‐formation dynamics measurements revealed the formation of two gratings of different natures resulting from the coupled mechanical and optical effects. A first grating, formed quickly upon exposure, is due to the photoisomerization of oriented azobenzene groups. A second grating, developed at longer exposure times, may originate from changes in the anisotropic structure of the SBS matrix, which is induced by the photochemical phase transition of azobenzene mesogens. The first grating is unstable, but the second grating remains in relaxed films. Both mechanisms can be enhanced by deformation of the film.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.002
Threshold uncertainty score0.005

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0020.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.022
GPT teacher head0.281
Teacher spread0.259 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations49
Published2003
Admission routes1
Has abstractyes

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