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Record W1986684898 · doi:10.1103/physreve.77.026105

Conduits of steady-state autocatalytic plumes

2008· article· en· W1986684898 on OpenAlexaff
Michael C. Rogers, Mick D. Mantle, Andrew J. Sederman, Stephen W. Morris

Bibliographic record

VenuePhysical Review E · 2008
Typearticle
Languageen
FieldPhysics and Astronomy
TopicNMR spectroscopy and applications
Canadian institutionsUniversity of Toronto
Fundersnot available
KeywordsBuoyancyPlumeEntrainment (biomusicology)MechanicsLaminar flowNeutral buoyancyAutocatalysisGeologyThermodynamicsMaterials scienceClassical mechanicsPhysicsKinetics

Abstract

fetched live from OpenAlex

Plumes are typically formed when a continuous source of buoyancy is supplied at a localized source. We studied laminar plumes where buoyancy is supplied by an autocatalytic chemical reaction: The iodate-arsenous acid (IAA) reaction. The nonlinear kinetics of the IAA reaction produces a sharp propagating front at which buoyancy is produced by exothermicity and compositional change. When the reaction is initiated in an unconfined volume of reactant, a starting plume with a mushroom shaped head connected to the initiation point by a long conduit is formed. After the initial transient during the ascent of the head, we observed the emergence of a steady state in the conduit morphology and flow. Autocatalytic plumes were compared to nonreacting, compositionally buoyant plumes using the Gradient Echo Rapid Velocity and Acceleration Imaging Sequence (GERVAIS), an MRI velocimetric technique. Autocatalytic conduits had axisymmetric bimodal velocity profiles and cone-shaped morphologies, in contrast to the Gaussian profiles and cylindrical shapes of nonreacting conduits. The bimodal distribution for autocatalytic plumes is a consequence of the unique effect of entrainment in this system. Rather than the usual effect of entrainment in nonreacting plumes, where less buoyant fluid is incorporated into the plumes, entrainment in autocatalytic plumes provides a buoyancy flux along the entire conduit by means of chemical reaction, thereby delocalizing the buoyancy source.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Theoretical or conceptual · Consensus signal: Theoretical or conceptual
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.530
Threshold uncertainty score0.371

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.025
GPT teacher head0.365
Teacher spread0.340 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designTheoretical or conceptual
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations10
Published2008
Admission routes1
Has abstractyes

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