Molecular Flexibility of Methylcelluloses of Differing Degree of Substitution by Combined Sedimentation and Viscosity Analysis
Why this work is in the frame
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Bibliographic record
Abstract
The flexibility/rigidity of methylcelluloses (MCs) plays an important part in their structure-function relationship and therefore on their commercial applications in the food and biomedical industries. In the present study, two MCs of low degree of substitution (DS) 1.09 and 1.32 and four of high DS (1.80, 1.86, 1.88 and 1.93) were characterised in distilled water in terms of intrinsic viscosity [h]; sedimentation coefficient (s020,w) and weight average molar mass (Mw). Solution conformation and flexibility were estimated qualitatively using conformation zoning and quantitatively (persistence length Lp) using the new combined global method. Sedimentation conformation zoning showed an extended coil (Type C) conformation and the global method applied to each MC sample yielded persistence lengths all within the range Lp(1/4)12-17 nm (for a fixed mass per unit length) with no evidence of any significant change in flexibility with DS.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.001 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it