Long‐Term Reactive Solute Transport in an Aquitard Using a Centrifuge Model
Bibliographic record
Abstract
Characterizing and predicting reactive solute transport in low hydraulic conductivity (K) clay-rich media is challenging because the very long transport time for solutes renders conventional column tests impractical. In this study, a centrifugation technique was developed to assess the transport of a simple aqueous solution (NaCl) by accelerating flow by centrifugal force through low K (1.1 x 10(-11) m/s) core samples. Duplicate cores (52-mm length x 33-mm diameter) were centrifuged at 330 xg for 90 d to model the migration of saline pore water (0.5 M NaCl) under in situ conditions through an approximately 17-m-thick clay prototype over approximately 24,000 years. A PHREEQC one-dimensional reactive solute transport code simulated effluent breakthrough of the NaCl during centrifugation, with best-fit cation exchange coefficients similar to batch tests. The calibrated code was used to predict solute profile development over the long term in the prototype or simulated field-scale conditions. Chromatographic separation of solutes due to ion exchange was evident over several meters in the simulated prototype and the field profile. The applicability of centrifugation methods to predict transport of more complex suites of reactive solutes over the long term is yet to be verified.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".