Reactivity of Poly(anilineboronic acid) with NAD<sup>+</sup> and NADH
Why this work is in the frame
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Bibliographic record
Abstract
The complexation of poly(anilineboronic acid) with β-nicotinamide adenine dinucleotide (NADH) and its oxidized form, NAD +, has been investigated using electrochemical and spectroscopic techniques. At neutral pH, cyclic voltammetry of poly(anilineboronic acid) exhibits redox activity in the presence of NADH and NAD + characteristic of self-doping. While complexation of both NADH and NAD + with poly(anilineboronic acid) is confirmed with polarization-modulated infrared reflection absorption spectroscopic measurements, a significant difference in redox behavior is observed. 11 B NMR studies suggest that the nature of species responsible for self-doping is different in the case of NAD + and NADH, where the presence of NAD + complex appears to facilitate the formation of the pernigraniline form of the polymer. In addition, a distinct difference in the sensitivity of open-circuit potential measurements is observed upon complexation with NADH and NAD + as a function of the oxidation state of polymer suggesting that reduction of the polymer occurs upon complexation of NADH. The mechanism responsible for the observed behavior is supported by quartz crystal microbalance measurements.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it