Spectroscopic characterization of the ZnNe van der Waals molecule in the<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msup><mml:mrow><mml:mi>X</mml:mi><mml:mn>0</mml:mn><mml:mn/></mml:mrow><mml:mrow><mml:mo>+</mml:mo></mml:mrow></mml:msup></mml:mrow><mml:mo>(</mml:mo><mml:mn>4</mml:mn><mml:mn/><mml:mrow><mml:msup><mml:mrow><mml:mi/></mml:mrow><mml:mrow><mml:mn>1</mml:mn></mml:mrow></mml:msup></mml:mrow><mml:mrow><mml:msub><mml:mrow><mml:mi>S</mml:mi></mml:mrow><mml:mrow><mml:mn>0</mml:mn></mml:mrow></mml:msub></mml:mrow><mml:mo>)</mml:mo></mml:math>and<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mi>D</mml:mi><mml:mn>1</mml:mn><mml:mo>(</mml:mo><mml:mn>4</mml:mn><mml:mn/><mml:mrow><mml:msup><mml:mrow><mml:mi/></mml:mrow><mml:mrow><mml:mn>1</mml:mn></mml:mrow></mml:msup></mml:mrow><mml:mrow><mml:msub><mml:mrow><mml:mi>P</mml:mi></mml:mrow><mml:mrow><mml:mn>1</mml:mn></mml:mrow></mml:msub></mml:mrow><mml:mo>)</mml:mo></mml:math>energy states
Bibliographic record
Abstract
A molecular jet-expansion beam of ZnNe seeded in Ne was crossed with a pulsed-laser beam produced by a Nd:YAG (yttrium aluminum garnet) laser-pumped dye laser. The dye laser was frequency doubled with a BBO-C second-harmonic-generation (SHG) crystal. Both the dye laser and the SHG were synchronously scanned over a range of $\ensuremath{\lambda}=2130--2170\AA{}$ in the vicinity of the Zn atomic $4{}^{1}{P}_{1}--4{}^{1}{S}_{0}$ resonance line (2138.65 \AA{}), producing an excitation spectrum related to the $D1(4{}^{1}{P}_{1})\ensuremath{\leftarrow}{X0}^{+}(4{}^{1}{S}_{0})$ transition in the ZnNe molecule. The spectral traces, which show a pronounced vibrational structure, were subjected to LeRoy's near-dissociation expansion (NDE) analysis, yielding ${\ensuremath{\omega}}_{e},$ ${\ensuremath{\omega}}_{e}{x}_{e},$ ${D}_{e},$ and long-range molecular potential parameters. Computer simulation of the excitation spectrum, based on a calculation of the Franck-Condon factors, yielded additional information on the equilibrium internuclear separation for the $D1$ and ${X0}^{+}$ states. The NDE analysis provided long-range characteristics for the ${X0}^{+}$ state of the CdNe and HgNe molecules as well. A simple dispersive model, and a combination rule for van der Waals interactions in the ground state of ZnNe, CdNe, and HgNe molecules, are discussed.
Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.
How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.012 | 0.012 |
| Meta-epidemiology (narrow) | 0.008 | 0.016 |
| Meta-epidemiology (broad) | 0.003 | 0.016 |
| Bibliometrics | 0.005 | 0.011 |
| Science and technology studies | 0.011 | 0.015 |
| Scholarly communication | 0.011 | 0.011 |
| Open science | 0.018 | 0.016 |
| Research integrity | 0.015 | 0.014 |
| Insufficient payload (model declined to judge) | 0.937 | 0.012 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; both teacher heads agree on what is shown here.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".