Photoinduced volume changes related to photoinduced anisotropy in chalcogenide glasses
Bibliographic record
Abstract
We report metastable photoinduced volume expansion (hyperexpansion) of up to 10 µm in height and several millimetres in diameter for the chalcogenide glass As 2 S 3 . This is an order of magnitude larger than reported to date in any material, including chalcogenide glasses. We suggest a model for the effect and propose that its origin is similar to the origin of photoinduced anisotropy in glassy chalcogenides proposed earlier. The model is based on the anisotropic chemical bonding found in most chalcogenide glasses; the anisotropy arises from the fact that chalcogen atoms exhibit both strong covalent bonding and weak van der Waals bonding. The origin of the photoinduced volume changes (expansion and contraction) is in a thermally induced diffusion, or athermal tunnelling, of photoexcited chalcogen atoms, with possible subsequent sublimation from the sample surface. The primary role of hyperpolarizable van der Waals bonds is supported by the absence of photoinduced volume changes in the chalcogenide glass Ga 1.4 La 0.6 S 3, in which chalcogen atoms do not bond via van der Waals bonds.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.002 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".