Diffusivity of Citric Acid During its Reaction With Calcite
Bibliographic record
Abstract
Summary The mass transfer process during the reaction of citric acid with calcite was investigated using a rotating disk apparatus. The effects of disk rotational speed, initial citric acid concentration and temperature on the effective diffusion coefficient of citric acid were examined. Using various citric acid concentrations (1 wt%, 2 wt%, 5 wt% and 7.5 wt%), the diffusion coefficient of citric acid was calculated at 25°C, 40°C and 50°C. The effective diffusion coefficient of citric acid was found to be a function of the interplay between the calcium citrate precipitation and the presence of the counter-calcium ions. At high-initial acid concentration (5 wt% and 7.5 wt%), the effects of calcium citrate precipitation and counter-calcium ions were significant and the calculated citric acid diffusion coefficients were not comparable with those obtained using the rotating disk. However, the effects of both the calcium citrate precipitation and the counter-calcium ions on the citric acid diffusivity were minimal at low-initial citric acid concentrations. The effect of temperature on the diffusion coefficient of citric acid at a constant citric acid concentration was found to follow Arrhenius law, and the activation energy was 37.9 kJ/mol.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.001 | 0.001 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.001 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".