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Record W1993137474 · doi:10.3139/217.1576

The Pressure-Volume-Temperature Behavior Polyethylene Melts

2000· article· en· W1993137474 on OpenAlex
L. Capt, Musa R. Kamal

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueInternational Polymer Processing · 2000
Typearticle
Languageen
FieldMaterials Science
TopicPolymer crystallization and properties
Canadian institutionsMcGill University
Fundersnot available
KeywordsMaterials sciencePolyethyleneDilatometerThermal expansionLinear low-density polyethyleneIsobaric processThermodynamicsCrystallizationCompressibilityLow-density polyethyleneVolume (thermodynamics)High-density polyethyleneIsothermal processMelting pointComposite material

Abstract

fetched live from OpenAlex

Abstract The pressure-volume-temperature (PVT) melt behavior of 12 polyethylene resins was evaluated at pressures up to 200 MPa, using both isothermal and isobaric measurements in a GNOMIX high pressure dilatometer. The resins included high density polyethylene (HDPE), low density polyethylene (LDPE) and linear low density polyethylene (LLDPE). They were produced using a variety of catalysts, including Ziegler-Natta (ZN) and metallocene catalysts. The PVT data were used to evaluate two empirical equations of state (the Tate and Inverse Volume equations) in predicting PVT behavior of the melt, the isothermal compressibility, and the thermal expansion coefficient. The dependence of the melting and crystallization temperatures on pressure was also evaluated, and compared to existing equations. It was not possible to identify structural effects on the PVT melt behavior, as well as the isothermal compressibility and thermal expansion coefficient. However, some slight dependence on density was observed for the parameters of the equations of state. The isobaric experiments revealed that the pressure effect on the melting and crystallization temperatures was similar for all resins. While the melting and crystallization temperatures varied widely for the various resins, the pressure coefficients of the melting and crystallization temperatures were approximately equal (0.25°C/MPa.) The main differences in the behavior of the resins were in the transitional region during melting and crystallization.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.242
Threshold uncertainty score0.995

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0010.000
Scholarly communication0.0010.001
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0060.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.247
Teacher spread0.238 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it