MétaCan
Menu
Back to cohort
Record W1993910656 · doi:10.1063/1.4819066

A new, low temperature long-pass cell for mid-infrared to terahertz spectroscopy and synchrotron radiation use

2013· article· en· W1993910656 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

fundA Canadian funder is recorded on the work.
no affNo Canadian affiliation: this work is invisible to an affiliation-only frame.
No Canadian affiliation. An affiliation-only frame, the usual design, would never have seen this work. It is one of the works that make the case for inverting the frame.

Bibliographic record

VenueReview of Scientific Instruments · 2013
Typearticle
Languageen
FieldChemistry
TopicSpectroscopy and Laser Applications
Canadian institutionsnot available
FundersCanadian Light Source
KeywordsCryostatOpticsBeamlineSpectroscopyMaterials scienceInfraredSynchrotron radiationOptical pathSpectrometerSynchrotronInfrared spectroscopySpectral resolutionPhysicsSpectral lineBeam (structure)

Abstract

fetched live from OpenAlex

A new cell has been designed for accurate spectroscopic measurements in the 80-400 K temperature range with variable path lengths from 3 to more than 141 m. The spectral coverage at these temperatures ranges from the visible to less than 10 cm(-1), thanks to the use of diamond windows. The design of the cryostat and vacuum setups allows vibration-free operation. The equipment provides temperature homogeneity and pressure control to better than 2% over the 100-400 K and the 0.1-1000 mbar ranges. Remote-controlled opto-mechanical systems enable in situ adjustments as well as changes of the optical path length within half an hour, in order to optimize measurement time in an open user facility. It allows then to meet the specific requirements of high resolution measurements on the Far-Infrared AILES beamline at SOLEIL as well at the LISA facility, in Créteil, in the mid-IR. This new instrument opens up the way for many experiments in the field of high-resolution gas-phase IR spectroscopy, in particular, in quantitative spectroscopy for atmospheric applications: measurements of absorption line parameters (absolute intensities, cross sections, and pressure-induced widths) using Fourier transform spectroscopy. The design and performance of the equipment are briefly presented and illustrated on spectroscopic examples.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.029
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.257
Teacher spread0.249 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it