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Extended Stern Model

2012· article· en· W2002610147 on OpenAlex
Rangadhar Pradhan, Analava Mitra, Soumen Das

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

venuePublished in a venue whose home country is Canada.
no affNo Canadian affiliation: this work is invisible to an affiliation-only frame.
No Canadian affiliation. An affiliation-only frame, the usual design, would never have seen this work. It is one of the works that make the case for inverting the frame.

Bibliographic record

VenueJournal of Applied Solution Chemistry and Modeling · 2012
Typearticle
Languageen
FieldChemistry
TopicElectrochemical Analysis and Applications
Canadian institutionsnot available
Fundersnot available
KeywordsSternCapacitanceElectrodeElectrolyteEquivalent circuitChemistryMaterials scienceElectrical engineeringVoltageEngineeringPhysical chemistry

Abstract

fetched live from OpenAlex

In this paper, a theoretical approach of extended Stern model is formulated to represent the electric double layer (EDL) for biochemical as well as biological samples. The existing Stern model is used for several decades to describe the phenomena of electric double layer of electrode/electrolyte interface. In the conventional stern model the double layer which is formed between the electrode and electrolyte interface is described by double layer capacitance. Using the existing Stern model, the equivalent circuit model is not valid for electrical double layer capacitance of electrode/electrolyte interface in β dispersion range. The protein molecules form chemical coupling and chemical adsorption along with classical ionic bonding with gold electrodes. Thus, the compactness of EDL decreases and the double layer capacitance is replaced by a constant phase element (CPE). In the present paper, a three-electrode based ECIS device was used to measure the impedance of various enzymatic solutions for practical realization of theoretical approach. The results obtained from experimental work, were simulated by equivalent circuit simulator, ZsimpWin to validate the extended Stern model by comparing χ2 value. Finally the electrical parameters were extracted and compared for Stern model and extended Stern model. The results obtained by practical experiment and equivalent circuit simulation showed the effectiveness of extended Stern model over Stern model.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.546
Threshold uncertainty score0.426

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.024
GPT teacher head0.263
Teacher spread0.238 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it