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Record W2007603555 · doi:10.1144/1467-7873/05-090

Comparison of metal distributions in snow, peat, lakes and humus around a Cu smelter in western Quebec, Canada

2006· article· en· W2007603555 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
aboutThe title or abstract carries a Canadian signal from the geographic lexicon.

Bibliographic record

VenueGeochemistry Exploration Environment Analysis · 2006
Typearticle
Languageen
FieldEnvironmental Science
TopicHeavy metals in environment
Canadian institutionsGeological Survey of Canada
Fundersnot available
KeywordsPeatSnowSmeltingHumusEnvironmental scienceEnvironmental chemistryPhysical geographyHydrology (agriculture)GeographySoil scienceGeologyChemistrySoil waterMeteorologyArchaeologyMetallurgyMaterials scienceGeotechnical engineering

Abstract

fetched live from OpenAlex

Concentrations of metals around the Cu smelter at Rouyn-Noranda, Québec, in snow, peat, the humus horizon of soil, lake water and sediments, show generally similar spatial distribution patterns. The contours of smelter-related metal concentrations in all these media are approximately circular in shape, centred on the smelter, and elongated somewhat towards the east due to the prevailing wind direction. Close to the smelter, the concentrations are up to 1000 times greater than regional background levels. The distances at which concentrations of smelter-related metals decrease to background levels is in the range 65 ± 5 km. The ratio of (Cu+As)/(Al+Fe) is a useful indicator of source apportionment for comparing the results between sampling media because it is independent of measurement units and maximizes the contrast between smelter and non-smelter materials. The value of the ratio, which changes as a function of distance from the smelter, reflects the mixing and dilution of emissions with non-smelter dust and aerosols. Deposition rates of metal calculated for snow and peat integrated over the area of the smelter-centred anomaly allow estimates to be made of the amounts of metal deposited from the smelter, after correcting for deposition of background metal. The proportions of reported metal emissions accounted for by deposition within 150 km of the smelter are: Cu, 25–50%; Pb, 10–20%; Zn, 25%; As, 5%; and Cd 20–25%. Metals in excess of these proportions are probably transported outside the immediate smelter footprint, but deposition of smelter-emitted metals becomes so small at these distances, and so mixed with airborne metals from other sources, that it is difficult to discriminate between smelter and non-smelter sources in samples taken on the ground.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.622
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.014
GPT teacher head0.242
Teacher spread0.228 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it