Report on Optical Absorption, Steady-state Emission and Time-resolved Emission Spectroscopy of Carbazole-based Conjugated Polymers
Bibliographic record
Abstract
Opto-electronic properties of three new carbazole based co-polymers were investigated. The decay kinetics of triplet emission of the co-polymers was observed. Several findings such as optical band-gap, singlet to singlet transition energies, triplet to singlet transition energies, exchange energies (?EST) have been presented. In comparison to the other material carbazole-oxadiazole based polymer with OMe, P1, H21C10, P2 and H12C10O, P3 exchange energy is below 0.5 eV and triplet energy is significantly higher. The energy gaps between singlet and triplet excited states are 0.44-0.47 eV. From decay kinetics the triplet excited state life-times were found to be several orders of ms at 10-13 K that reduces to less than 3 ms at room temperature.Keywords: Time resolved emission spectroscopy; Carbazole; Conjugated polymers.© 2011 JSR Publications. ISSN: 2070-0237 (Print); 2070-0245 (Online). All rights reserved.doi:10.3329/jsr.v3i1.4666 J. Sci. Res. 3 (1), 13-24 (2011)
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.001 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".