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Record W2012588837 · doi:10.3749/canmin.49.2.651

NISNITE, Ni3Sn, A NEW NICKEL MINERAL SPECIES FROM THE JEFFREY MINE, ASBESTOS, QUEBEC

2011· article· en· W2012588837 on OpenAlexaffvenueabout
R. Rowe, Joel D. Grice, Glenn Poirier, C. J. Stanley, László Horváth

Bibliographic record

VenueThe Canadian Mineralogist · 2011
Typearticle
Languageen
FieldMaterials Science
TopicIron-based superconductors research
Canadian institutionsCanadian Museum of Nature
Fundersnot available
KeywordsElectron microprobeNickelMineralCrystallographyDiopsideFormula unitChromiteMetalCrystal structureMaterials scienceMineralogyAnalytical Chemistry (journal)ChemistryMetallurgy

Abstract

fetched live from OpenAlex

Nisnite, ideally Ni 3 Sn, was found during a re-examination of heazlewoodite crystals in rodingite samples from the Jeffrey mine, Asbestos, Quebec. It occurs as bronze-colored metallic, striated, blocky and square to rectangular tabular crystals of up to 100 μm in length, with groupings of ≤1 mm growing on heazlewoodite. Crystal groupings exhibit a boxwork-like habit. Reflectance measurements in air gave 43.2 (470 nm), 49.1 (546 nm), 53.2 (589 nm), and 59.0% (650 nm). Minerals closely associated with nisnite are chromite, diopside, grossular, heazlewoodite and shandite. The mineral is cubic, P 4/ m 32/ m , with unit-cell parameter refined using powder-diffraction data: a 3.7349(6) A, V 52.10(3) A 3 , Z = 1, D calc = 9.41 g/cm 3 . The average results of five and three electron-microprobe analyses on separate crystals gave Ni 57.88, Sn 40.17, sum 98.05 wt.% and Ni 59.24, Sn 41.00, sum 100.24 wt.%, corresponding to Ni 2.98 Sn 1.02 on the basis of 4 apfu . The structure has been refined to an R index of 0.008% on the basis of 30 unique reflections. The structure of nisnite contains 12-coordinated Sn atoms (12 Ni) and 12-coordinated Ni atoms (8 Ni and 4 Sn). Among the three synthetic Ni 3 Sn phases known, nisnite corresponds to the ccp structure that has been synthesized at high pressure and high temperature.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesInsufficient payload (model declined to judge)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: Not applicable
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.359
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0010.001
Scholarly communication0.0000.000
Open science0.0020.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0120.002

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.083
GPT teacher head0.249
Teacher spread0.165 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; both teacher heads agree on what is shown here.

Study designNot applicable
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations7
Published2011
Admission routes3
Has abstractyes

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