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Record W2013314037 · doi:10.1002/pssc.200675790

Defects in diamond

2007· article· en· W2013314037 on OpenAlexaff
S. Dannefaer

Bibliographic record

VenuePhysica status solidi. C, Conferences and critical reviews/Physica status solidi. C, Current topics in solid state physics · 2007
Typearticle
Languageen
FieldMaterials Science
TopicDiamond and Carbon-based Materials Research
Canadian institutionsUniversity of Winnipeg
Fundersnot available
KeywordsDiamondVacancy defectImpurityMaterial properties of diamondPositronMaterials scienceCondensed matter physicsSemiconductorDopingElectron paramagnetic resonanceAnnihilationAtomic physicsChemistryElectronNuclear magnetic resonancePhysicsNuclear physicsOptoelectronicsMetallurgy

Abstract

fetched live from OpenAlex

Abstract Diamond is one of the remarkable forms of carbon. For example, it can be found in nature with an impurity content of less than 1 ppm, or it can be synthesized either as a single‐crystal or as a polycrystalline deposit on various surfaces. Furthermore, boron doping makes it a p‐type semiconductor, and even superconducting. Diamond is also one of the few materials where optical absorption (OA) yields relevant information on defects, including the omnipresent nitrogen impurity. This is so because in diamond many defects have sharp zero‐phonon lines. Irradiation produces vacancies and interstitials both of which have been identified by OA and electron paramagnetic resonance, and also by positron annihilation (vacancy only). Irradiation‐produced defects are remarkable stable, with the monovacancy becoming mobile at 700 °C, and the divacancy surviving to at least 1000 °C. In this contribution are reviewed relevant aspects of diamond physics and what positron annihilation has contributed so far. Diamond provides the opportunity for a correlation between optical absorption and positron results, including the difficult issue of the electrical charge of a defect. Such combined experiments are presently searching for the elusive positively charged monovacancy in irradiated B doped single crystalline diamond. Future positron experiments could with benefit be aimed at investigating vacancy impurity complexes, such as the one claimed by OA as a four nitrogen‐vacancy complex. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.002
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Theoretical or conceptual · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.489
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0020.001
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0020.000
Bibliometrics0.0000.001
Science and technology studies0.0000.001
Scholarly communication0.0010.001
Open science0.0010.001
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.055
GPT teacher head0.383
Teacher spread0.328 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designTheoretical or conceptual
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations19
Published2007
Admission routes1
Has abstractyes

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