Part III: Supercritical Fluid Chromatographic Separations
Why this work is in the frame
A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.
Bibliographic record
Abstract
The enantioseparation of 123 clinically used racemic drugs by supercritical fluid chromatography (SFC) on commercial chiral stationary phases (CSPs) available in 2006 is reviewed. The CSPs were briefly described in Part I of this work. The mobile phase compositions, with organic modifier and additives, are listed. The data was extracted and compiled from the ChirBase database (Marseille, France). All the drugs included are listed according to the thirteen therapeutic classes of the Anatomical Therapeutic Chemical (ATC) classification. It is evident that the nature of the SF mobile phase precludes the use of several classes of CSPs such as the crown ethers, ligand‐exchange or protein‐based CSPs. The polysaccharide based CSPs were responsible for two third of the enantiomer separation listed.
Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.003 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it