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pH-responsive permeability of PE-g-PMAA membranes

2000· article· en· W2015156342 on OpenAlexaff
Tao Peng, Yu‐Ling Cheng

Bibliographic record

VenueJournal of Applied Polymer Science · 2000
Typearticle
Languageen
FieldEnvironmental Science
TopicMembrane Separation Technologies
Canadian institutionsUniversity of Toronto
Fundersnot available
KeywordsMembraneMethacrylic acidPolymer chemistryPermeability (electromagnetism)SwellingSolventGraftingChemical engineeringMonomerMaterials scienceWettingChemistryPolymerComposite materialOrganic chemistry

Abstract

fetched live from OpenAlex

Poly(methacrylic acid) (PMAA) grafted porous PE membranes (PE-g-PMAA) were studied. It was found that (1) a wide range of graft yields can be achieved by varying irradiation time (20–240 min) and monomer concentration (0.22M–0.66M), (2) the grafted membrane exhibits reversible permeability response, (3) the membrane shows a maximum permeability response at an intermediate permeant molecular weight due to size exclusion effect, and (4) depending on the graft yield, two types of permeability response can be obtained. These observations are consistent with our earlier study on poly(N-isopropylacrylamide) (PNIPAAm)–grafted porous polyethylene membranes. In addition, it was observed that the solvent used during grafting may influence the graft location—presumably due to variations in pore wetting. Specifically, compared to water solvent, methanol can increase grafting inside membrane pores, an observation inferred from membrane swelling, thickness measurement, and SEM characterization. Moreover, preferential grafting inside the membrane pores, as affected by increasing methanol content in the grafting solvent, results in lower membrane permeability and a greater pore graft-controlled type of permeability response. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 76: 778–786, 2000

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.003

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0000.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.243
Teacher spread0.234 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations63
Published2000
Admission routes1
Has abstractyes

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