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Record W2015185386 · doi:10.1179/cmq.2000.39.4.405

Thermodynamic Evaluation and Optimization of the LiCl-NaCl-KCl-RbCl-CsCl-MgCl<sub>2</sub>-CaCl<sub>2</sub>-SrCl<sub>2</sub>System Using The Modified Quasichemical Model

2000· article· en· W2015185386 on OpenAlex
Patrice Chartrand, A. D. Pelton

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueCanadian Metallurgical Quarterly · 2000
Typearticle
Languageen
FieldEngineering
TopicMetallurgical Processes and Thermodynamics
Canadian institutionsPolytechnique Montréal
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsPhase diagramThermodynamicsChemistryPhase equilibriumTernary operationTernary numeral systemPhase (matter)Physical chemistryPhysicsComputer science

Abstract

fetched live from OpenAlex

AbstractAbstractA complete critical evaluation and quantitative optimization of all available phase diagrams and thermodynamic data has been performed for all condensed phases of the LiCl-NaCl-KCl-RbCl-CsCl-MgCl2-CaCl2-Srcl2 system. The present article treats the addition of Srcl2 to this database. The model parameters obtained for binary and ternary subsystems can be used to predict thermodynamic properties and phase equilibria for the multicomponent system. The modified quasichemical model for short-range ordering was used for the molten salt phase.Une évaluation critique et une optimization quantitative des diagrammes de phase et des données thermodynamiques a été faite pour toutes les phases condensées du système LiCl-NaCl-KCl-RbCl-CsCl-MgCl2-CaCl2-Srcl2. Le présent article porte sur l'addition de Srcl2 à cette base de données. Les paramètres des modèles obtenus pour les sous-systèmes binaires et ternaires peuvent être utilisés pour prédire les propriétés thermodynamiques et les équilibres de phases pour le système multicomposant. Le modèle quasichimique modifié, qui évalue l'ordonnement à courte distance des cations, a été utilisé pour la phase liquide.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: Simulation or modeling
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.199
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0000.001
Science and technology studies0.0010.000
Scholarly communication0.0000.001
Open science0.0010.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.012
GPT teacher head0.203
Teacher spread0.191 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it