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Record W2015312861 · doi:10.1063/1.4830401

Effect of an external electric field on the diffusion-influenced geminate reversible reaction of a neutral particle and a charged particle in three dimensions. III. Ground-state ABCD reaction

2013· article· en· W2015312861 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueThe Journal of Chemical Physics · 2013
Typearticle
Languageen
FieldBiochemistry, Genetics and Molecular Biology
TopicDiffusion and Search Dynamics
Canadian institutionsUniversity of Toronto
Fundersnot available
KeywordsChemistryElectric fieldLaplace transformDiffusionGround stateKinetic energyPower lawDomain (mathematical analysis)Field (mathematics)Particle (ecology)PhysicsAtomic physicsThermodynamicsQuantum mechanicsMathematical analysisMathematicsStatistics

Abstract

fetched live from OpenAlex

In the presence of an external electric field, the ground-state \documentclass[12pt]{minimal}\begin{document}$A+B^q \rightleftharpoons C^q + D$\end{document}A+Bq⇌Cq+D diffusion-influenced reversible reaction for a geminate pair, a neutral and a charged particle, is investigated in three dimensions. The probability density functions, the rates of reactions, and the survival probabilities of individual particles are analytically derived in the Laplace domain in terms of series solutions. The long-time kinetics of probability density functions and rates of reactions in rescaled forms shows a kinetic transition behavior from a t−3/2 power law to a t−3/2et increase when the condition \documentclass[12pt]{minimal}\begin{document}$D_1F_1^2 \le D_2F_2^2$\end{document}D1F12≤D2F22, which depends on the diffusivities of particles and the external electric fields, changes to \documentclass[12pt]{minimal}\begin{document}$D_1F_1^2 > D_2F_2^2$\end{document}D1F12>D2F22. In the transition region \documentclass[12pt]{minimal}\begin{document}$D_1F_1^2 = D_2F_2^2$\end{document}D1F12=D2F22, the long-time behavior also shows a t−3/2 power law decay but with a different value of the prefactor. The rescaled survival probabilities only exhibit an exponentially increasing behavior at long times with no dependence on the various values of parameters.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.008
Threshold uncertainty score0.194

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.007
GPT teacher head0.246
Teacher spread0.239 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it