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Record W2016640769 · doi:10.1039/c3ta10355b

Naphthalene-based poly(arylene ether ketone) anion exchange membranes

2013· article· en· W2016640769 on OpenAlexaff
Zhuang Liu, Xiaobai Li, Kunzhi Shen, Pengju Feng, Yinan Zhang, Xu Xu, Wei Hu, Zhenhua Jiang, Baijun Liu, Michael D. Guiver

Bibliographic record

VenueJournal of Materials Chemistry A · 2013
Typearticle
Languageen
FieldEngineering
TopicFuel Cells and Related Materials
Canadian institutionsNational Research Council Canada
FundersPeople's Government of Jilin ProvinceNational Natural Science Foundation of China
KeywordsAryleneMembraneKetoneIon exchangeEtherChemistryPolymer chemistryThermal stabilityPolymerizationNaphthaleneIonic bondingPolymerIonOrganic chemistryAlkyl

Abstract

fetched live from OpenAlex

Naphthalene-based poly(arylene ether ketone)s were obtained through a three-step process involving polymerization of methylated polymers, followed by bromination and derivatization with a diquaternary-ammonium group. The ionic conductivities of the anion exchange membranes were above 10−2 S cm−1 at room temperature and the membrane with an IEC = 1.46 mequiv. g−1 attained an ion conductivity of 7.4 × 10−2 S cm−1 at 100 °C, which is higher than many reported results. The membrane series had low water uptake and excellent dimensional stability, even at the highest IEC values. In addition, the membranes were insoluble in organic solvents and concentrated alkaline solutions for many days, even under heating, suggesting their excellent stability. These combined data suggest that the membranes have potential to be used as anion exchange membranes for fuel cells applications.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.010
Threshold uncertainty score0.990

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0110.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.192
Teacher spread0.184 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations71
Published2013
Admission routes1
Has abstractyes

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