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Record W2021116532 · doi:10.1002/apj.274

Mercury and halides emissions from 200 MW pulverized coal combustion boiler

2009· article· en· W2021116532 on OpenAlexaboutno aff
Hui Wu, Jianrong Qiu, Shunlin Tang, Hao Liu, Quanhai Wang, Hancai Zeng

Bibliographic record

VenueAsia-Pacific Journal of Chemical Engineering · 2009
Typearticle
Languageen
FieldEnvironmental Science
TopicMercury impact and mitigation studies
Canadian institutionsnot available
FundersNational Science Fund for Distinguished Young ScholarsNational Natural Science Foundation of China
KeywordsFlue gasMercury (programming language)Boiler (water heating)Electrostatic precipitatorPulverized coal-fired boilerChemistryHalideCombustionEnvironmental chemistryCoal combustion productsCoalWaste managementFly ashFlue-gas emissions from fossil-fuel combustionInorganic chemistryEngineering

Abstract

fetched live from OpenAlex

Abstract Mercury emission from coal‐fired power plants is the major industrial source of mercury pollution in China. For a better understanding about the coal combustion Hg emission in China, a field measurement was conducted on a 200 MW pulverized coal fired boiler. Halides being proved to be mercury transformation participators, the U.S. EPA (Environmental Protection Agency) recommended Ontario Hydro method (OHM) and EPA Method 26A were adopted to determine the speciation of Hg and halides in postcombustion flue gases, respectively. Results indicated that, as the flue gas cooling down, the percentage of oxidized mercury in total gas phase mercury (Hg2+(g)/HgT(G)) increased from 41% to about 74% across the electrostatic precipitator (ESP) outlet. Oxidized mercury (Hg2+(g)) was more apt to be absorbed onto the fly ash. The main halides measured in flue gas were HF and HCl, while the concentrations of Cl2 and HBr were extremely low and no Br2 was detected in flue gas. Analysis indicated that acid flue gas components, such as HCl, HF, SO2 and NO, showed a certain extent of promotion on Hg oxidation. The measured mercury emission factor (EMF) in this test was 5.63 g/1012J (13.1 lb/1012Btu). Copyright © 2009 Curtin University of Technology and John Wiley & Sons, Ltd.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.006
Threshold uncertainty score0.013

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0020.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.220
Teacher spread0.211 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations6
Published2009
Admission routes1
Has abstractyes

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