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Record W2023307361 · doi:10.2166/wst.2000.0539

Bioremediation of highly energetic compounds: a search for remediation technologies

2000· article· en· W2023307361 on OpenAlex
Jalal Hawari, Chun Fang Shen, Charles W. Greer, Denis Rho, Geoffrey I. Sunahara, Guy Ampleman, Sonia Thiboutot

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueWater Science & Technology · 2000
Typearticle
Languageen
FieldEnvironmental Science
TopicMicrobial bioremediation and biosurfactants
Canadian institutionsBiotechnology Research Institute
Fundersnot available
KeywordsMineralization (soil science)ChemistryBioremediationBiotransformationPhanerochaeteBiodegradationEnvironmental chemistryTolueneEnvironmental remediationTrinitrotolueneNuclear chemistrySlurryOrganic chemistryContaminationEnvironmental engineeringNitrogen

Abstract

fetched live from OpenAlex

When TNT (N-source) was treated with anaerobic sludge it biotransformed into triaminotoluene (TAT) in high yield (80%). Results of experiments using 13C-labeling indicate that denitrated or deaminated products such as p-cresol and toluene were not formed. Whereas 14C-labeling showed negligible mineralization (<0.1% 14CO2) despite the complete disappearance of TNT. On the other hand, when TNT (175 μM) was treated with the fungus Phanerochaete chrysosporium it disappeared completely in less than two weeks, but mineralization (liberated 14CO2) did not exceed 1%. Several intermediates, marked with the initial formation of the two monohydroxylamino-dinitrotoluene (HADNT) followed by their transformation to monoamino-dinitrotoluenes (ADNT), diamines (DANT), acetylated TNT products, and azo and hydrazo derivatives were detected. In contrast, high concentrations (ca 20,000 ppm) of RDX and HMX were effectively degraded (ca 70%) in soil slurries using municipal anaerobic sludge. RDX and HMX disappearance was accompanied by the elimination of toxicity associated with RDX and HMX as determined by the Microtox test.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.033
Threshold uncertainty score0.771

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.002
Science and technology studies0.0000.002
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.225
Teacher spread0.215 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it