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Omongwaite, Na<sub>2</sub>Ca<sub>5</sub>(SO<sub>4</sub>)<sub>6</sub>.3H<sub>2</sub>O, a new mineral from recent salt lake deposits, Namibia

2008· article· en· W2032166974 on OpenAlexaff
Florias Mees, Frédéric Hatert, Ralph Rowe

Bibliographic record

VenueMineralogical Magazine · 2008
Typearticle
Languageen
FieldChemical Engineering
TopicChemical and Physical Properties in Aqueous Solutions
Canadian institutionsCanadian Museum of Nature
FundersUniversiteit GentUniversiteit AntwerpenFonds De La Recherche Scientifique - FNRSKU LeuvenUniversity of Bristol
KeywordsMonoclinic crystal systemCrystallographyCrystal structureElectron microprobeMineralogyChemistryStructural formula

Abstract

fetched live from OpenAlex

Abstract Omongwaite, Na 2 Ca 5 (SO 4 ) 6 .3H 2 O, is a new mineral, found as inclusions in gypsum crystals in recent salt lake deposits at Omongwa pan, Namibia. It is monoclinic, with space group C2, a = 12.08(3) A, b = 6.96(1) Å, c = 6.39(2) Å, B = 90.2(3)°, V= 537(2) Å 3 , and Z = 1. The six strongest lines in the X-ray powder diffraction pattern [d obs . (Å), (I/I ° meas ), (hkl)] are: 6.028, (40), (110); 3.484, (29), (310); 3.019, (51), (400); 3.014, (100), (220); 2.824, (34), (1̄12); and 2.820, (65), (112). Electron microprobe analysis, recalculated on the basis of 3H 2 O per formula unit (p.f.u.), gave 56.16 wt.% SO 3 , 30.82 wt.% CaO, 5.25 wt.% Na 2 O, 3.21 wt.% K 2 O, 6.25 wt.% H 2 O, totalling 101.69 wt.%. The empirical formula, based on 24 anhydrous oxygens p.f.u., is (Na 1.47 K 0.59 ) Σ;=2.06 Ca 4.76 S 6.07 O 24 .3H 2 O, yielding Na 2 Ca 5 (-SO 4 ) 6 .3H 2 O as the end-member formula. Na/K ratios are variable, with an average of ∼2.5. The crystals are elongated, with pseudohexagonal transversal cross-sections and with sphenoidal terminations that are commonly developed at one end. The crystal structure of omongwaite is similar to that of bassanite, CaSO 4 .0.5H 2 O. Published studies of the synthetic phase show that it can be described as a bassanite structure in which one out of six Ca 2+ ions are replaced by Na + and a second Na + ion occupies a position near those sites. The crystals are parallel to the [001] axis of the gypsum crystals in which they occur as inclusions. The mineral formed by topotactic replacement during interaction of gypsum with concentrated solutions. It is preserved where the affected surface became covered by gypsum by rapid growth shortly after the formation of omongwaite. The mineral is named after the locality where it was found.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.002
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Research integrity, Insufficient payload (model declined to judge)
Consensus categoriesMeta-epidemiology (narrow), Research integrity
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.078
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.002
Meta-epidemiology (narrow)0.0030.003
Meta-epidemiology (broad)0.0040.002
Bibliometrics0.0010.003
Science and technology studies0.0010.002
Scholarly communication0.0000.001
Open science0.0020.002
Research integrity0.0020.005
Insufficient payload (model declined to judge)0.0000.004

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.019
GPT teacher head0.210
Teacher spread0.191 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; both teacher heads agree on what is shown here.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations14
Published2008
Admission routes1
Has abstractyes

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