Intermittent and spatially heterogeneous single-particle dynamics close to colloidal gelation
Bibliographic record
Abstract
Dynamical heterogeneities exist ubiquitously in materials near a dynamical arrest transition, such as glass formation or gelation. Among the readily discernible features of heterogeneous dynamics is a non-Gaussian exponential component in the distribution of the constituent particle displacements that is not understood at the single-particle level. We present an experimental study of particle dynamics and self-van Hove functions G_{s}(r,t) in a colloid-polymer system approaching gelation. We show experimental evidence, in the special case of a gelation transition, for exponentially distributed times for anomalously large displacements, and confirm that an exponential tail in G_{s} arises from rare events with associated Poisson statistics. We focus on the role of the anomalous large displacements and analyze their time scales, relating them to other time scales typically used to describe structural relaxation in gels and glasses: the time to cage breakup and the time for re-emergence of Fickian behavior at long times. Furthermore, we search for a structural origin of the dynamical heterogeneity. Various quantities characterizing local structure are examined. We found evidence of a strong correlation between local structure and local dynamics, in contrast to what has been found in supercooled liquids.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".