New combination bands of N2O-CO2, N2O-OCS, and N2O-N2 complexes in the N2O ν1 region
Bibliographic record
Abstract
Spectra of the weakly bound complexes N2O-CO2, N2O-OCS, and N2O-N2 were studied in the region of the ν1 fundamental of N2O (∼2224 cm(-1)) using a tunable quantum cascade laser to probe a pulsed supersonic jet expansion with an effective rotational temperature of about 2.5 K. One new combination band was observed for each complex: a band involving an intermolecular in-plane bending mode for N2O-N2, a band involving the disrotation (in-plane geared bend) for of N2O-CO2, and a band involving the out-of-plane torsional vibration for isomer b of N2O-OCS. Small perturbations were noted for the N2O-OCS band. Because of the absence of theoretical prediction, the nature of the intermolecular bending mode for N2O-N2 has not been identified. The resulting intermolecular frequencies are 34.175(1), 17.107(1), and 22.334(1) cm(-1) for N2O-CO2, N2O-OCS, and N2O-N2, respectively. In addition, the previously known fundamental band of N2O-N2 at 2225.99 cm(-1) was analyzed in improved detail. This band exhibits very weak a-type transitions which were not detected in the first infrared observation of this complex, indicating that N2O-N2 is not exactly T-shaped. That is, the N2O molecular axis is not exactly perpendicular to the a-inertial axis, in agreement with a previous structural determination of this complex by rotational spectroscopy.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".