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Record W2039680608 · doi:10.1021/ie050953b

Rapid Development of New Polymer Blends:  The Optimal Selection of Materials and Blend Ratios

2006· article· en· W2039680608 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueIndustrial & Engineering Chemistry Research · 2006
Typearticle
Languageen
FieldChemistry
TopicSpectroscopy and Chemometric Analyses
Canadian institutionsMcMaster University
Fundersnot available
KeywordsRaw materialSelection (genetic algorithm)Process engineeringComputer scienceProcess (computing)Materials sciencePolymer blendYield (engineering)Product (mathematics)Material selectionFinal productDegrees of freedom (physics and chemistry)PolymerBiochemical engineeringMathematicsComposite materialEngineeringThermodynamicsChemistry

Abstract

fetched live from OpenAlex

A data-based approach to the development of industrial polymer blends with specified final properties is presented. There are basically three major degrees of freedom to control the final product properties: the selection of raw materials, the selection of the ratios in which to blend them, and the selection of process conditions used to manufacture them. In this paper, we present a new optimization approach that simultaneously addresses all of these degrees of freedom, but the primary focus will be on the selection of the materials and their ratios. The approach involves building partial least-squares (PLS) models that combine databases on previously made blends and databases on the properties of the component materials used in these blends. The resulting models are then used in an optimization framework to select raw materials from much larger databases (including materials never previously used) and to select the ratios in which to blend them in order to yield a blend product with specified end properties at a minimum cost. The methodology is applied to two industrial polymer blending problems that involve the replacement of raw materials while keeping the same product properties and minimizing total raw material cost.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.002
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0020.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.062
GPT teacher head0.313
Teacher spread0.251 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it