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Record W2043175959 · doi:10.1103/physrevb.66.064103

Universal relaxor polarization in<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mi mathvariant="normal">Pb</mml:mi><mml:mo>(</mml:mo><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">Mg</mml:mi></mml:mrow><mml:mrow><mml:mn>1</mml:mn><mml:mo>/</mml:mo><mml:mn>3</mml:mn></mml:mrow></mml:msub></mml:mrow><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">Nb</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn><mml:mo>/</mml:mo><mml:mn>3</mml:mn></mml:mrow></mml:msub></mml:mrow><mml:mo>)</mml:mo><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">O</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>and related materials

2002· article· lv· W2043175959 on OpenAlexaff
Alexei A. Bokov, Zuo‐Guang Ye

Bibliographic record

VenuePhysical review. B, Condensed matter · 2002
Typearticle
Languagelv
FieldMaterials Science
TopicFerroelectric and Piezoelectric Materials
Canadian institutionsSimon Fraser University
Fundersnot available
KeywordsPhysicsFerroelectricityCondensed matter physicsOrder (exchange)CrystallographyDielectricQuantum mechanicsChemistry

Abstract

fetched live from OpenAlex

The dielectric permittivity \ensuremath{\varepsilon} at frequencies from ${(10}^{\ensuremath{-}1}--{10}^{\ensuremath{-}5})\mathrm{Hz}$ to ${10}^{5}\mathrm{Hz}$ is studied in perovskite $(1\ensuremath{-}x)\mathrm{Pb}({\mathrm{Mg}}_{1/3}{\mathrm{Nb}}_{2/3}){\mathrm{O}}_{3}\ensuremath{-}x{\mathrm{PbTiO}}_{3}$ relaxor ferroelectric ceramics of different compositions $x=0.35,$ 0.25, and 0, which exhibit, below the temperature of the diffuse $\ensuremath{\varepsilon}(T)$ maximum ${T}_{m},$ a tetragonal ferroelectric, a rhombohedral ferroelectric, and a nonergodic relaxor phase, respectively. The universal relaxor dispersion previously observed at temperatures near and above ${T}_{m}$ in the ceramics of $x=0.25$ is also found to exist in other compositions. This dispersion is described by the fractional power dependence of the real and imaginary parts of susceptibility on frequency, ${\ensuremath{\chi}}_{U}^{\ensuremath{'}}(f)\ensuremath{\propto}{\ensuremath{\chi}}_{U}^{\ensuremath{''}}(f)\ensuremath{\propto}{f}^{n\ensuremath{-}1}.$ The real part of the universal relaxor susceptibility ${\ensuremath{\chi}}_{U}^{\ensuremath{'}}$ is only a comparatively small fraction of the total permittivity ${\ensuremath{\varepsilon}}^{\ensuremath{'}},$ but ${\ensuremath{\chi}}_{U}^{\ensuremath{''}}$ is the dominant contribution to the losses in a wide frequency-temperature range above ${T}_{m}.$ In the high-temperature phase a divergent temperature behavior is observed, ${\ensuremath{\chi}}_{U}^{\ensuremath{'}}(T)\ensuremath{\propto}(T\ensuremath{-}{T}_{0}{)}^{\ensuremath{-}\ensuremath{\gamma}}$ and ${\ensuremath{\chi}}_{U}^{\ensuremath{''}}(T)\ensuremath{\propto}(T\ensuremath{-}{T}_{0}{)}^{\ensuremath{-}\ensuremath{\gamma}},$ with ${T}_{0}&lt;{T}_{m}$ and $\ensuremath{\gamma}\ensuremath{\cong}2,$ for all the three compositions studied. The universal relaxor susceptibility is attributed to the polarization of polar nanoregions, which are inherent in the relaxor ferroelectrics. A microscopic model of this polarization is proposed, according to which the dipole moments of some ``free'' unit cells inside the polar nanoregion can freely choose several different directions, while the direction of the total moment of the nanoregion remains the same. The ensemble of interacting polar nanoregions is described in terms of a standard spherical model, which predicts the quadratic divergence of susceptibility above the critical temperature, in agreement with the experimental results.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.002
metaresearch head score (Gemma)0.004
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: none
Teacher disagreement score0.423
Threshold uncertainty score0.823

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0020.004
Meta-epidemiology (narrow)0.0020.002
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0010.002
Science and technology studies0.0020.001
Scholarly communication0.0030.005
Open science0.0030.003
Research integrity0.0020.004
Insufficient payload (model declined to judge)0.4230.218

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.015
GPT teacher head0.238
Teacher spread0.222 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations68
Published2002
Admission routes1
Has abstractyes

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