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Record W2048279793 · doi:10.1117/12.570059

Multi-species gas detection with long-wavelength VCSEL

2004· article· en· W2048279793 on OpenAlexafffund
A. Lytkine, Wolfgang Jäeger, J. Tulip

Bibliographic record

VenueProceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE · 2004
Typearticle
Languageen
FieldChemistry
TopicSpectroscopy and Laser Applications
Canadian institutionsUniversity of Alberta
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsLaserMaterials scienceTrace gasAbsorption (acoustics)WavelengthAbsorption spectroscopyOpticsSpectroscopyBar (unit)Vertical-cavity surface-emitting laserAnalytical Chemistry (journal)Spectral lineOptoelectronicsPhysicsChemistry

Abstract

fetched live from OpenAlex

A long-wavelength VCSEL has been used for the first time for multi-species gas detection and for trace gas sensing. The VCSEL with a buried tunnel junction (VERTILAS, Germany) was capable of covering a spectral range of 7 nm or 28 cm<sup>-1</sup> (central wavelength at 1576.3 nm) with the laser temperature and injection current varied between 0-50 °C and 0.5-5 mA respectively. The pressure of CO:CO<sub>2</sub>=3:2 gas mixtures buffered with N<sub>2</sub> (N<sub>2</sub> content 0 - 90 %) was varied from 1 mBar up to 1 Bar. To avoid a non-linear dynamic tuning, the combination of a direct injection current with a saw-tooth waveform was used to sweep the laser frequency across absorption lines. A LabVIEW-based computer code was developed for multi-species gas analysis in time domain. Absorption spectra were averaged over 10<sup>2</sup>-10<sup>3</sup> laser scans. It has been shown that a cross interference from all collisional partners should be taken into account for accurate multi-component gas detection. A concentration of 600 ppm of CO<sub>2</sub> in atmospheric air (fractional absorption ~ 10<sup>-4</sup>) was detected with laser output power of 120 uW. Long-wavelength VCSELs can be used both for multi-species gas detection in a wide range of pressures and for trace gas monitoring.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.133
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.227
Teacher spread0.215 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations5
Published2004
Admission routes2
Has abstractyes

Explore more

Same venueProceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIESame topicSpectroscopy and Laser ApplicationsFrench-language works237,207