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Record W2048583832 · doi:10.1021/ef900653x

Correlation for the Effective Gas Diffusion Coefficient in Carbon Paper Diffusion Media

2009· article· en· W2048583832 on OpenAlexafffund
Nada Zamel, Xianguo Li, Jun Shen

Bibliographic record

VenueEnergy & Fuels · 2009
Typearticle
Languageen
FieldEngineering
TopicFuel Cells and Related Materials
Canadian institutionsBC Innovation CouncilUniversity of Waterloo
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsDiffusionEffective diffusion coefficientGaseous diffusionPorous mediumElectrolytePlane (geometry)PorosityCorrelation coefficientMaterials scienceChemistryThermodynamicsMechanicsPhysicsPhysical chemistryComposite materialElectrodeMathematicsStatistics

Abstract

fetched live from OpenAlex

The understanding of mass transport limitations in polymer electrolyte membrane (PEM) fuel cells is crucial in the research and progress of this technology. The structure of the components, specifically the as diffusion layer (GDL), of PEM fuel cells, is complex. Thus, for the purpose of simulating mass transport in the GDL, the effect of the structure on the diffusion coefficient is taken into account by introducing an effective diffusion coefficient. The effective diffusion coefficient of a gas is lower than its corresponding bulk diffusion coefficient due to the presence of a solid matrix in the porous materials. Currently, the Bruggeman approximation is the most widely used correlation for estimating the effective diffusion coefficient in the GDL. Other semiempirical models are also available. However, these correlations overestimate the effective diffusion coefficient due to the assumptions on which they are based. In this study, correlations for the through-plane and in-plane diffusibility in the GDL are developed based on a three-dimensional (3D) simulation of gas diffusion in the GDL. The 3D structure of the TORAY carbon paper with no binding material is reconstructed using stochastic models and used as the modeling domain. The numerical results are shown to have a good agreement with experimental data of diffusibility in both directions. Correlations for two different porosity ranges are given.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.405
Threshold uncertainty score0.418

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.004
GPT teacher head0.183
Teacher spread0.179 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designSimulation or modeling
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations139
Published2009
Admission routes2
Has abstractyes

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