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LOW-POWER LASER IGNITION OF ALUMINUM/METAL OXIDE NANOTHERMITES

2014· article· en· W2048691711 on OpenAlexaff
Cătălin Florin Petre, Daniel Chamberland, Tommy Ringuette, Sophie Ringuette, Suzanne Paradis, Robert Stowe

Bibliographic record

VenueInternational Journal of Energetic Materials and Chemical Propulsion · 2014
Typearticle
Languageen
FieldEngineering
TopicEnergetic Materials and Combustion
Canadian institutionsDefence Research and Development Canada
Fundersnot available
KeywordsThermiteMaterials scienceThermogravimetric analysisLaser ignitionIgnition systemDifferential scanning calorimetryScanning electron microscopeLaserAnalytical Chemistry (journal)Autoignition temperatureOxideAluminiumChemical engineeringComposite materialOpticsMetallurgyChemistry

Abstract

fetched live from OpenAlex

In this study, three different types of nanothermites, i.e., Al/CuO, MoO3, and Al/Bi2O3, were produced using the widely spread wet (i.e., isopropanol based) method. In addition to the above method, the three nanothermites were also produced using a Resodyn LabRAM mixer. A paraffin-coated spherical Al nanopowder (100 nm) was used as the fuel source, while the oxidizers were nanometric powders of CuO (40 nm), MoO3 (100 nm), and Bi2O3 (200 nm). The effect of nanothermite composition on the sensitivity for the tests of electrostatic discharge (ESD), impact, and friction was investigated. Scanning electron microscopy (SEM) was used to analyze the morphology and homogeneity of the nanothermites. Next, the nanothermites were thermally analyzed in terms of energy release, ignition temperature, and flame temperature using a thermogravimetric analysis differential and scanning calorimetry (TGA/DSC) technique. A low-power diode laser was used to evaluate the ability of different laser wavelengths (661, 532, and 445 nm) to produce the ignition energy needed for a specific thermite reaction. Low ignition delays (less than 15 ms) were obtained at approximately 300 mW laser power output for both Al/MoO3 and Al/Bi2O3 thermites. Finally, a forward-looking infrared camera was used to estimate the ignition and burning temperatures of the Al/MoO3 nanothermite.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.003
Threshold uncertainty score0.437

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.003
GPT teacher head0.189
Teacher spread0.186 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations9
Published2014
Admission routes1
Has abstractyes

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