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Record W2049693423 · doi:10.1021/ac053302y

Petroleomics: MS Returns to Its Roots.

2005· article· en· W2049693423 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

aboutThe title or abstract carries a Canadian signal from the geographic lexicon.
no affNo Canadian affiliation: this work is invisible to an affiliation-only frame.
No Canadian affiliation. An affiliation-only frame, the usual design, would never have seen this work. It is one of the works that make the case for inverting the frame.

Bibliographic record

VenueAnalytical Chemistry · 2005
Typearticle
Languageen
FieldComputer Science
TopicGeochemistry and Geologic Mapping
Canadian institutionsnot available
FundersDivision of ChemistryNational High Magnetic Field LaboratoryOhio State UniversityHigh Magnetic Field Laboratory, Chinese Academy of SciencesFlorida State UniversityNational Science Foundation
KeywordsCitationAltmetricsSocial mediaIconComputer scienceWorld Wide WebLibrary scienceInformation retrieval

Abstract

fetched live from OpenAlex

AS ince its commercial birth, MS has been intimately tied to the petrochemical industry- petroleum producers sell molecules, and therefore oil's chemical composition determines its economic value.The composition of the oil also determines both its upstream (production) and downstream (processing) behavior.Determining the composition of those species that contain the heteroatoms nitrogen, sulfur, and oxygen is especially important, because these species contribute to solid deposition, flocculation, catalyst deactivation, storage instability, and refinery corrosion problems, and these factors affect the efficiency with which we collectively use our finite world petroleum reserve.The supply of "light" sweet crudes is diminishing, and the world oil market is therefore shifting toward "heavier" crudes rich in heteroatoms.Characterization of these heavier crudes is limited because of their immense complexity.For oil companies, compositional knowledge equals power-the power to develop oil reserves more efficiently, predict production problems, prevent pipe fouling and failures, reduce refining byproducts and waste, make money, and better manage the world's oil reserve.National security issues are also of concern because of the political instability of many oil-rich nations.North and South America are relatively secure regions and have substantial petroleum reserves, albeit of lower quality, namely heavy crude oil or tar sand.For example, the province of Alberta, Canada, rests on a substantial petroleum reserve.Alberta tar sands alone contain an estimated reserve of ~2 trillion barrels or ~175 billion barrels of recoverable crude oil, compared with Saudi Arabia's ~260 billion barrels of crude oil.The North and South American sources produce heavy, heteroatomic-rich crudes, and they will continue to do so for the immediate future.Compositional knowledge of these crudes could improve production and processing and subsequently reduce our dependence on Middle Eastern oil.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: none
Teacher disagreement score0.804
Threshold uncertainty score0.684

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.013
GPT teacher head0.241
Teacher spread0.228 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it