Vibrational moments of fundamental transitions in low-temperature molecular liquids: Determination from the band shape of vibrations in the overtone spectral range
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Bibliographic record
Abstract
It is shown that the integrated absorption coefficients of strong fundamental bands of some gaseous substances can be determined with an accuracy of 5–10% using experimental data on the spectral moments of bands in the overtone spectral range of these substances in the liquid phase near the melting point. The absorption coefficients are calculated within the framework of the cell model of the liquid state from the contributions of the resonance dipole-dipole interaction to the second spectral moment. The combination and overtone absorption bands of the SF 6 , CF 4 , SiF 4 , NF 3 , CHF 3 , CC1F 3 , CBrF 3 , OCS, N 2 O, and CO 2 molecules in the liquid state and in solutions in liquefied Xe, Kr, and O 2 are recorded. The data in the literature on the intensity of strong IR bands in the gas phase are analyzed. Using an improved experimental technique, additional measurements are performed. It is found that the absorption coefficients determined from the spectral characteristics of the liquids agree well with the coefficients measured in the gas phase.
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Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
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