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Effect of High Hydrostatic Pressure on the Secondary Structures of BSA and Apo‐ and Holo‐α‐Lactalbumin Employing Fourier Transform Infrared Spectroscopy

2002· article· en· W2052068815 on OpenAlexaff
Tahereh Hosseini-nia, Ashraf A. Ismail, Stan Kubow

Bibliographic record

VenueJournal of Food Science · 2002
Typearticle
Languageen
FieldAgricultural and Biological Sciences
TopicProteins in Food Systems
Canadian institutionsMcGill University
Fundersnot available
KeywordsChemistryFourier transform infrared spectroscopyBovine serum albuminProtein secondary structureInfrared spectroscopyHydrostatic pressureDenaturation (fissile materials)LactalbuminInfraredSpectroscopyAnalytical Chemistry (journal)CrystallographyBiophysicsChromatographyBiochemistryNuclear chemistryOrganic chemistryChemical engineering

Abstract

fetched live from OpenAlex

ABSTRACT Conformational changes in bovine serum albumin (BSA), Ca ++ ‐free α‐lactalbumin(apo‐α‐lac), and Ca ++ ‐saturated α‐lactalbumin(holo‐ct‐lac) were examined via Fourier transform infrared (FTIR) spectroscopy after pressure treatment up to 1270 MPa. BSA showed minimal irreversible secondary structural changes with pressurization, showing a slight loss of β‐sheet structure in favor of α‐helix. Apo‐α‐lac underwent major irreversible changes and exhibited infrared bands characteristic of aggregation upon decompression. Holo‐α‐lac showed extensive resistance to high pressure with no major structural changes. The rich disulfide content in BSA and the presence of Ca ++ in holo‐α‐lac may play important roles in stabilizing these proteins against pressure denaturation.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.044
Threshold uncertainty score0.206

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.014
GPT teacher head0.222
Teacher spread0.208 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations30
Published2002
Admission routes1
Has abstractyes

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