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Record W2053551548 · doi:10.1002/celc.201402124

Biotemplated Palladium Catalysts Can Be Stabilized on Different Support Materials

2014· article· en· W2053551548 on OpenAlexfundno aff
Matthew D. Yates, Bruce E. Logan

Bibliographic record

VenueChemElectroChem · 2014
Typearticle
Languageen
FieldMaterials Science
TopicConducting polymers and applications
Canadian institutionsnot available
FundersHuck Institutes of the Life SciencesMcMaster University
KeywordsCatalysisGraphiteMaterials sciencePalladiumPolydimethylsiloxaneElectrochemistryElectrodeCarbon fibersPolyanilineNafionChemical engineeringComposite materialComposite numberPolymerChemistryOrganic chemistry

Abstract

fetched live from OpenAlex

Abstract Sustainably biotemplated palladium catalysts generated on different carbon‐based support materials are examined for durability under electrochemical (oxidative) and mechanical‐stress conditions. Biotemplated catalysts on carbon paper under both stresses retain 95 % (at 0.6 V) of the initial catalytic activity as opposed to 70 % for carbon cloth and 60 % for graphite. Graphite electrodes retain 95 % of initial catalytic activity under a single stress. Using electrodeposited polyaniline (PANI) and polydimethylsiloxane binder increases the current density after the stress tests by 22 %, as opposed to a 30 % decrease for Nafion. PANI‐coated electrodes retain more activity than carbon‐paper electrodes under elevated mechanical (94 versus 70 %) or increased oxidative (175 versus 62 %) stress. Biotemplated catalytic electrodes may be useful alternatives to synthetically produce catalysts for some electrochemical applications.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.003
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0020.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.019
GPT teacher head0.252
Teacher spread0.233 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations13
Published2014
Admission routes1
Has abstractyes

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