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Record W2053556272 · doi:10.1021/ie0100941

High-Shear-Rate Behavior of Radial Hydrogenated Styrene−Isoprene and Block Ethylene−Propylene Copolymer Solutions

2001· article· en· W2053556272 on OpenAlexaff
David Erickson, Dongqing Li, Tony M. White, Jason Gao

Bibliographic record

VenueIndustrial & Engineering Chemistry Research · 2001
Typearticle
Languageen
FieldChemical Engineering
TopicRheology and Fluid Dynamics Studies
Canadian institutionsImperial Oil (Canada)University of Toronto
Fundersnot available
KeywordsIsopreneShear rateCopolymerMaterials scienceEthylene propylene rubberShear thinningShear (geology)PolymerStyreneEthylene oxidePolymer chemistryComposite materialViscosity

Abstract

fetched live from OpenAlex

Using a capillary viscometry technique, the high-shear-rate behavior of two polymer additives (an ethylene−propylene block copolymer and a radial hydrogenated styrene−isoprene copolymer) in a hydrocarbon-based oil solution has been investigated. At mass concentrations of up to 2.0% for the styrene−isoprene copolymer and 1.5% for the ethylene−propylene additive, the viscosity was measured over a range of shear rates from 10 4 to 10 6 s -1 . To correct for the effects of viscous heating and pressure changes, a numerical correction procedure is used which reduces the experimental results to viscosity data at a common reference temperature and pressure for comparison. Over the range of shear rates examined, the styrene−isoprene solutions exhibited typical shear-thinning behavior, becoming more dramatic at higher polymer concentrations. In addition to shear thinning at the higher shear rates, a shear-thickening region was observed in the more concentrated ethylene−propylene solutions. As the polymer concentration increased, the degree of shear thickening was shown to be more severe and the critical region was observed at lower shear rates.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.003

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.061
GPT teacher head0.297
Teacher spread0.236 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations3
Published2001
Admission routes1
Has abstractyes

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