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Record W2056926073 · doi:10.1002/aoc.183

Biomethylation and bioaccumulation of arsenic(V) by marine alga <i>Fucus gardneri</i>

2001· article· en· W2056926073 on OpenAlex
S. C. R. Granchinho, Elena Polishchuk, Walter Cullen, Kenneth J. Reimer

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.
aboutThe title or abstract carries a Canadian signal from the geographic lexicon.

Bibliographic record

VenueApplied Organometallic Chemistry · 2001
Typearticle
Languageen
FieldEnvironmental Science
TopicArsenic contamination and mitigation
Canadian institutionsRoyal Military College of CanadaUniversity of British Columbia
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsChemistryArsenateFucusArsenicFucus vesiculosusEnvironmental chemistryBioaccumulationArseniteAlgaeSeawaterInductively coupled plasma mass spectrometryChromatographyBotanyMass spectrometryEcologyBiology

Abstract

fetched live from OpenAlex

Abstract The brown alga, Fucus gardneri , was collected from Vancouver Island, B.C., Canada. Fucus samples were acclimated in seawater and then exposed to arsenic(V) in artificial seawater, all under axenic conditions. The arsenic species in the Fucus samples were extracted into 1:1 methanol/H 2 O and identified by using ion‐pairing high‐performance liquid chromatography coupled to inductively coupled plasma mass spectrometry (HPLC–ICP‐MS). Anion‐exchange HPLC–ICP‐MS was used to identify the arsenic species in the growth medium. It was found that ∼73% of the original arsenosugars in the F. gardneri samples were lost during the acclimation period. Arsenite [As(III)] and dimethylarsenate [DMA] concentration increased in the Fucus samples after exposure to arsenate [As(V)]. A small increase in the concentration of an arsenosugar was seen during this period, accompanied by a further decrease in the concentration of two other arsenosugars. The experiments provided very little evidence for the hypothesis that arsenosugars are produced by the macroalgae. Copyright © 2001 John Wiley &amp; Sons, Ltd.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.056
Threshold uncertainty score0.995

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0060.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.004
GPT teacher head0.181
Teacher spread0.178 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it