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Record W2058330012 · doi:10.1021/jp9919157

Rotamer-Specific Potentials of Mean Force for Residue Pair Interactions

2000· article· en· W2058330012 on OpenAlexaff
Alexandre S. Lemak, John R. Gunn

Bibliographic record

VenueThe Journal of Physical Chemistry B · 2000
Typearticle
Languageen
FieldBiochemistry, Genetics and Molecular Biology
TopicProtein Structure and Dynamics
Canadian institutionsUniversité de Montréal
Fundersnot available
KeywordsConformational isomerismAmino acid residuePotential of mean forceResidue (chemistry)Monte Carlo methodChemistryUmbrella samplingStatistical physicsMolecular dynamicsComputational chemistryMoleculeMathematicsPhysicsStatisticsPeptide sequence

Abstract

fetched live from OpenAlex

We present an approach for the development of knowledge-based mean-force potentials for representing residue−residue interactions in proteins at the amino acid level of resolution which take into account the rotamer states of the residues. The rotamer-specific potentials which consist of an additional correction term to the current database-derived statistical potentials are expressed in terms of distance-dependent mean force potentials (MFP). To describe the relative geometry of two residues we used a set of six distances between different pairs of atoms. The distant-dependent MFPs are calculated from computer simulations of each pair of amino acids at the atomic level using the weighted-histogram analysis method. The umbrella sampling for each of 52003 different rotamer pairs was performed with a force-bias Monte Carlo algorithm using molecular mechanics potentials with statistically derived restraint terms. Our simulations show that the MFPs are very sensitive to the rotamer states of the amino acid residues. Preliminary tests of the potential's performance show that it can reproduce side-chain packing with reasonable accuracy.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.003
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: Simulation or modeling
GenreCandidate signal: Empirical · Consensus signal: none
Teacher disagreement score0.002
Threshold uncertainty score0.008

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.003
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0010.001
Science and technology studies0.0010.001
Scholarly communication0.0010.001
Open science0.0020.001
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0020.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.007
GPT teacher head0.250
Teacher spread0.243 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designSimulation or modeling
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations8
Published2000
Admission routes1
Has abstractyes

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Same venueThe Journal of Physical Chemistry BSame topicProtein Structure and DynamicsFrench-language works237,207