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Record W2058710066 · doi:10.1002/jccs.200100066

Hydrogen‐rare Gas Interactions and Raman Line Shapes

2001· article· en· W2058710066 on OpenAlexaff
Levi Waldron, Wing‐Ki Liu

Bibliographic record

VenueJournal of the Chinese Chemical Society · 2001
Typearticle
Languageen
FieldChemistry
TopicSpectroscopy and Laser Applications
Canadian institutionsUniversity of TorontoUniversity of Waterloo
Fundersnot available
KeywordsChemistryRaman spectroscopyIsotropyAnisotropyLine (geometry)Spectral lineIntermolecular forceAtomic physicsMixing (physics)Rare gasMolecular physicsHydrogenMoleculeOpticsPhysicsQuantum mechanicsGeometry

Abstract

fetched live from OpenAlex

Abstract Employing the recent XC(fit) intermolecular potential for H 2 ‐Ar, we have presented the results of the spectral parameters for the D 2 ‐Ar Raman Q 1 branch, obtained from quantum mechanical close‐coupled calculations. While the theoretical line shifts of the polarized Raman spectra were found to agree with experiments, the corresponding widths were smaller than the measured values by as much as 56%. We observed that the shifts and the widths depend on the vibrational dependence of the potential in their own separate ways, and our results suggested that the anisotropic vibrational dependence of the XC(fit) potential requires improvement, in conjunction with further fine‐tuning of the isotropic part. Even though there is no experimental data for comparison, we have computed the line‐mixing parameters of the polarized Raman Q 1 branch, as well as the depolarized line widths and shifts for the Q 1 ( j ) lines. These results showed the same trends as the corresponding ones for D 2 ‐He.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.052
Threshold uncertainty score0.665

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.273
Teacher spread0.265 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations4
Published2001
Admission routes1
Has abstractyes

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