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Record W2058782129 · doi:10.1029/2007jc004462

An annual study of inorganic and organic nitrogen and phosphorus and silicic acid in the southeastern Beaufort Sea

2008· article· en· W2058782129 on OpenAlexaff
Kyle G. Simpson, Jean‐Éric Tremblay, Yves Gratton, Neil M. Price

Bibliographic record

VenueJournal of Geophysical Research Atmospheres · 2008
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicMarine and coastal ecosystems
Canadian institutionsInstitut National de la Recherche ScientifiqueUniversité LavalMcGill University
Fundersnot available
KeywordsHaloclineWater columnNitrateOceanographyPhytoplanktonNitrogenSalinitySilicic acidSeawaterEnvironmental chemistryAmmoniumPhosphorusOrganic matterNutrientChemistryGeology

Abstract

fetched live from OpenAlex

Water column samples from the Mackenzie Shelf, the Beaufort Sea, and the Amundsen Gulf were obtained during 2003–2004 to investigate nutrient dynamics in an Arctic ecosystem influenced by a large river and flaw lead polynya. Nutrient inventories in the upper water column showed a significant seasonal drawdown of nitrate (NO3−) and silicic acid (Si(OH)4) (1:1.75 mol/mol) and subsequent accumulation of nitrite (NO2−) and ammonium (NH4+). Dissolved organic nitrogen and phosphorus concentrations (DON and DOP) were elevated in surface waters during the time of peak phytoplankton growth (bloom and postbloom phases) and covaried in a 17:1 molar ratio. Vertical profiles showed the typical middepth maxima in NO3−, PO43−, and Si(OH)4 at salinity 32–33.1. The concentration of DOP (0.76 ± 0.27 μmol P L−1) was also 2 times higher in this layer compared to the surface average and inversely correlated with the water mass tracer N* [N* = (NO3− − 16 × PO43− + 2.9) × 0.87], suggesting that Pacific‐derived waters were a source of the enrichment. Below the mixed layer, DON was generally constant with depth, although averaged profiles (like those of urea) suggested the presence of subsurface maxima at 50 m and between 250 and 300 m. Regeneration ratios varied with depth and were approximately 9.0 mol −O2/mol NO3− and 122.5 mol −O2/mol PO43− in shallow Pacific‐derived waters (halocline layer) and 17.4 and 193.5 in deep Atlantic waters (Atlantic layer), respectively. Deep waters of the Amundsen Gulf contained an excess of 1.7 μmol NO3− L−1, 0.12 μmol PO43− L−1, and 6.2 μmol Si(OH)4 L−1 and a deficit in O2, relative to waters of similar density in the Beaufort Sea, in proportions consistent with the remineralization ratios derived from oxygen‐nutrient regressions. Enhanced export of particulate matter from the overlying polynya and subsequent remineralization at depth are hypothesized to create this nutrient enrichment.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.223
Threshold uncertainty score0.442

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.001
Science and technology studies0.0010.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.021
GPT teacher head0.265
Teacher spread0.244 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations65
Published2008
Admission routes1
Has abstractyes

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