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Record W2063785440 · doi:10.1021/ed084p1159

Resveratrol Photoisomerization: An Integrative Guided-Inquiry Experiment

2007· article· en· W2063785440 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueJournal of Chemical Education · 2007
Typearticle
Languageen
FieldChemistry
TopicVarious Chemistry Research Topics
Canadian institutionsMcMaster University
Fundersnot available
KeywordsPhotoisomerizationAbsorbanceChemistrySample (material)Analytical Chemistry (journal)Biochemical engineeringBiological systemChromatographyOrganic chemistryCatalysisEngineeringIsomerization

Abstract

fetched live from OpenAlex

A kinetic study of trans–cis resveratrol photoisomerization was developed as a model guided-inquiry experiment for third-year undergraduate students to bridge the gap between explicitly prescribed laboratories and independent fourth-year research projects. Resveratrol photoisomerization was performed directly in a NMR tube within a UV photochemical reactor during which aliquots of sample were removed and diluted at specific time intervals for UV absorbance and HPLC measurements, whereas NMR spectra were performed directly in the original sample. Students in small groups are directly involved in the planning and organization of the experiment along with subsequent data analysis to statistically compare the apparent rate constant and half-life. Students appreciate the advantages and limitations of each technique with respect to quantitative and qualitative analyses, as well as understanding the photochemical properties of a recently discovered natural phytochemical with important biological properties relevant to human health. Students are also provided the opportunity to repeat the experiment to improve their technique and assess the reliability of their results. Our main objective was to promote inquiry-based learning in students within a defined experimental setting that integrates several fundamental concepts and instrumental techniques as a way to better prepare students for independent research in chemical biology.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.011
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.030
GPT teacher head0.385
Teacher spread0.355 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it