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Record W2066072680 · doi:10.1029/2006jd007782

Comparison of Canadian air quality forecast models with tropospheric ozone profile measurements above midlatitude North America during the IONS/ICARTT campaign: Evidence for stratospheric input

2007· article· en· W2066072680 on OpenAlexaffabout
D. W. Tarasick, Michael D. Moran, Anne M. Thompson, Trevor Carey‐Smith, Yves Rochon, V. S. Bouchet, Paul A. Makar, Craig Stroud, Sylvain Ménard, Louis-Philippe Crevier, Sophie Cousineau, Janusz A. Pudykiewicz, A. Kallaur, R. Moffet, Richard Ménard, A. Robichaud, Owen R. Cooper, S. J. Oltmans, J. C. Witte, G. Forbes, B. J. Johnson, J. T. Merrill, J. L. Moody, Gary A. Morris, Michael J. Newchurch, F. J. Schmidlin, E. Joseph

Bibliographic record

VenueJournal of Geophysical Research Atmospheres · 2007
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicAtmospheric chemistry and aerosols
Canadian institutionsTechnical University of Nova ScotiaEnvironment and Climate Change Canada
FundersNational Oceanic and Atmospheric Administration
KeywordsTropospheric ozoneOzoneTroposphereEnvironmental scienceAtmospheric sciencesMiddle latitudesAltitude (triangle)StratosphereMixing ratioOzone layerPlanetary boundary layerClimatologyMeteorologyGeographyGeologyMathematics

Abstract

fetched live from OpenAlex

During July and August, 2004, balloon‐borne ozonesondes were released daily at 12 sites in the eastern USA and Canada, producing the largest single set of free tropospheric ozone measurements ever compiled for this region. At the same time, a number of air quality forecast models were run daily as part of a larger field experiment. In this paper, we compare these ozonesonde profiles with predicted ozone profiles from several versions of two of these forecast models, the Environment Canada CHRONOS and AURAMS models. We find that the models show considerable skill at predicting ozone in the planetary boundary layer and immediately above. Individual station biases are variable, but often small. Standard deviations of observation‐forecast differences are large, however. Ozone variability in the models is somewhat higher than observed. Most strikingly, none of the model versions is able to reproduce the typical tropospheric ozone profile of increasing mixing ratio with altitude. Results from a sensitivity test suggest that the form of the ozone lateral boundary condition used by all model versions contributes significantly to the large ozone underpredictions in the middle and upper troposphere. The discrepancy could be reduced further by adding a downward flux of ozone from the model lid and by accounting for in situ production of ozone from lightning‐generated NOx.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.003
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.035
Threshold uncertainty score0.108

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.003
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0000.001
Bibliometrics0.0010.001
Science and technology studies0.0010.000
Scholarly communication0.0020.001
Open science0.0020.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.156
GPT teacher head0.369
Teacher spread0.213 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations48
Published2007
Admission routes2
Has abstractyes

Explore more

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