Metallic state induced in Eu2Ru2O7 by hole creation and orbital overlap in the <i>t</i>2<i>g</i> bands
Bibliographic record
Abstract
Two different series of ruthenium pyrochlores with the compositions Eu2−xCaxRu2O7 (0 ≤ x ≤ 0.6) and Eu2Ru2−xRexO7 (0 ≤ x ≤ 0.4) were prepared via solid state reaction, and their transport and magnetic properties were investigated. In both systems, the resistivity is shifted from 106 Ω cm to 10−3 Ω cm at low temperatures with increasing doping. The series correspond to two different approaches for inducing a metal–insulator transition in the Eu2Ru2O7 parent compound: (i) the substitution of Eu3+ by Ca2+, resulting in hole creation within the Ru t2g bands, and (ii) the partial substitution of Ru4+ (4d4) by Re4+ (5d3), leading to hole creation and an increase in the orbital overlap. Increasing the Ca or Re concentration suppresses the anomalies observed for Eu2Ru2O7 in dc magnetic susceptibility under zero-field-cooled and field-cooled conditions at 118 K and 23 K. In addition, a small negative magnetoresistance was obtained at low temperatures for doped samples with 2% Ca and Re.
Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.
How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.001 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".