Metallic state induced in Eu2Ru2O7 by hole creation and orbital overlap in the <i>t</i>2<i>g</i> bands
Bibliographic record
Abstract
Two different series of ruthenium pyrochlores with the compositions Eu2−xCaxRu2O7 (0 ≤ x ≤ 0.6) and Eu2Ru2−xRexO7 (0 ≤ x ≤ 0.4) were prepared via solid state reaction, and their transport and magnetic properties were investigated. In both systems, the resistivity is shifted from 106 Ω cm to 10−3 Ω cm at low temperatures with increasing doping. The series correspond to two different approaches for inducing a metal–insulator transition in the Eu2Ru2O7 parent compound: (i) the substitution of Eu3+ by Ca2+, resulting in hole creation within the Ru t2g bands, and (ii) the partial substitution of Ru4+ (4d4) by Re4+ (5d3), leading to hole creation and an increase in the orbital overlap. Increasing the Ca or Re concentration suppresses the anomalies observed for Eu2Ru2O7 in dc magnetic susceptibility under zero-field-cooled and field-cooled conditions at 118 K and 23 K. In addition, a small negative magnetoresistance was obtained at low temperatures for doped samples with 2% Ca and Re.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".