Rotating ring-disk voltammetric investigations on the degradation rate of the nickel(III)-glycylglycyl-<scp>L</scp>-histidine complex
Bibliographic record
Abstract
The voltammetric behavior of the Ni(II)/glycylglycyl-L-histidine complex and the degradation of the electrogenerated Ni(III) species were investigated by cyclic voltammetry. Results of electrochemical and spectrophotometric experiments indicated some differences in the nature and reactivity of Ni(III) complexes formed by two independent routes, i.e., anodic oxidation of Ni(II) and homogeneous oxidation by an autocatalytic reaction in a medium containing oxygen and S(IV) (H 2 SO 3 , HSO [Formula: see text] , and SO[Formula: see text]). The Ni(III) species formed electrochemically reacts in a fast chemical process (EC mechanism) and the observed rate constant of the degradation (k = 0.17 s –1 ) was determined by a rotating ring-disk electrode technique measuring kinetic collection efficiency values as a function of the rotation rate. Key words: nickel, glycylglycyl-L-histidine, sulfite, degradation reaction, rotating ring-disk voltammetry.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.002 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.001 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.001 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".