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Record W2073397663 · doi:10.1002/chin.200622013

Syntheses of [F<sub>5</sub>TeNH<sub>3</sub>][AsF<sub>6</sub>], [F<sub>5</sub>TeN(H)Xe][AsF<sub>6</sub>], and F<sub>5</sub>TeNF<sub>2</sub> and Characterization by Multi‐NMR and Raman Spectroscopy and by Electronic Structure Calculations: The X‐Ray Crystal Structures of α‐ and β‐F<sub>5</sub>TeNH<sub>2</sub>, [F<sub>5</sub>TeNH<sub>3</sub>][AsF<sub>6</sub>], and [F<sub>5</sub>TeN(H)Xe][AsF<sub>6</sub>].

2006· article· en· W2073397663 on OpenAlexaff
Barbara A. Fir, J. Marc Whalen, Hélène P. A. Mercier, David A. Dixon, Gary J. Schrobilgen

Bibliographic record

VenueChemInform · 2006
Typearticle
Languageen
FieldChemistry
TopicInorganic Fluorides and Related Compounds
Canadian institutionsMcMaster University
Fundersnot available
KeywordsChemistryRaman spectroscopyCharacterization (materials science)CrystallographyX-rayCrystal structureNanotechnologyOpticsPhysics

Abstract

fetched live from OpenAlex

Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.008
metaresearch head score (Gemma)0.004
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Meta-epidemiology (broad), Science and technology studies, Scholarly communication, Open science, Research integrity
Consensus categoriesMeta-epidemiology (narrow), Science and technology studies, Research integrity
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.059
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0080.004
Meta-epidemiology (narrow)0.0210.021
Meta-epidemiology (broad)0.0180.006
Bibliometrics0.0070.012
Science and technology studies0.0100.014
Scholarly communication0.0070.011
Open science0.0090.008
Research integrity0.0160.019
Insufficient payload (model declined to judge)0.0000.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.004
GPT teacher head0.191
Teacher spread0.187 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; both teacher heads agree on what is shown here.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2006
Admission routes1
Has abstractyes

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