Headgroup Motion in a Lyotropic Lamellar Phase by Deuterium and Nitrogen-14 Relaxation Studies
Bibliographic record
Abstract
Deuterium (2H) and nitrogen-14 (14N) NMR spectroscopy were used to investigate the molecular dynamics of a lyotropic liquid crystal. Deuterium spectral densities of motion for the C1 deuterated site on the chain of the molecule decylammonium chloride (DACl) at the Larmor frequency 61.4 MHz and those for the (14)N at the headgroup (NH(3)(+)) at 28.9 MHz are analyzed quantitatively in the lamellar phase of the DACl-d(11)/water binary system to shed light on the headgroup dynamics. The motional model used is the small step rotational diffusion for reorientations plus internal rotations of the methylene group in the strong collision limit. The tumbling motion of the long axis of the DACl molecule in the aggregates seems to be as rigorous as the molecular spinning motion, likely due to the proposed motional model. The similarity of deuterium spectral densities from the C1 and C2/C3 sites may indicate a relatively rigid unit of C1-C2-C3 in the backbone.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".