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Record W2074271793 · doi:10.1021/cg034136v

Effects of Glycerol and Tween 60 on the Crystallization Behavior, Mechanical Properties, and Microstructure of a Plastic Fat

2003· article· en· W2074271793 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueCrystal Growth & Design · 2003
Typearticle
Languageen
FieldAgricultural and Biological Sciences
TopicFood Chemistry and Fat Analysis
Canadian institutionsUniversity of Guelph
FundersNatural Sciences and Engineering Research Council of CanadaOntario Ministry of Food and Agriculture
KeywordsCrystalliteGlycerolNucleationCrystallizationChemistryCrystal (programming language)MicrostructureYield (engineering)Materials scienceAnalytical Chemistry (journal)CrystallographyChemical engineeringThermodynamicsChromatographyOrganic chemistryComposite material

Abstract

fetched live from OpenAlex

The addition of 0.10% glycerol or Tween 60 increased the yield force of a 70:30 (w/w) mixture of triolein/HMF (high-melting fraction of milkfat) at 5 °C. Further increases in glycerol or Tween 60 caused a decrease in yield force. Solid fat content (SFC) versus time profiles at 30 °C (glycerol) and 28 °C (Tween 60) allowed for the determination of Avrami rate constants of crystallization ( k ) and Avrami exponents ( n ). Higher Avrami constants and lower Avrami indices (higher rate of crystal growth), smaller crystallites, and a shorter induction time of nucleation were observed in samples containing 0.10% Tween 60 relative to the control and 0.50% Tween 60. A 0.10% glycerol addition, on the other hand, yielded opposite results. The increase in hardness induced by small additions of Tween 60 could be attributed to decreases in crystallite size at constant SFC and fractal dimension. The increase in hardness induced by small additions of glycerol could only be attributed to increases in the crystal-melt interfacial tension, at constant SFC and fractal dimension, despite increases in crystallite size.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.009
Threshold uncertainty score0.160

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.019
GPT teacher head0.180
Teacher spread0.161 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it