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Record W2074502109 · doi:10.1039/b809939a

Performance and low temperature behaviour of hydrous ruthenium oxide supercapacitors with improved power densities

2008· article· en· W2074502109 on OpenAlexaff
Xiaorong Liu, Peter G. Pickup

Bibliographic record

VenueEnergy & Environmental Science · 2008
Typearticle
Languageen
FieldMaterials Science
TopicSupercapacitor Materials and Fabrication
Canadian institutionsMemorial University of Newfoundland
Fundersnot available
KeywordsSupercapacitorCapacitancePower densityAnalytical Chemistry (journal)Ruthenium oxideCyclic voltammetryMaterials scienceEquivalent series resistanceElectrodeOxideCurrent densitySeparator (oil production)ChemistryElectrochemistryElectrical engineeringThermodynamicsPower (physics)VoltageChromatographyPhysical chemistryMetallurgy

Abstract

fetched live from OpenAlex

The performances of hydrous Ru oxide supercapacitors have been characterized by cyclic voltammetry, constant current discharge, and impedance experiments. The effective series resistance (ESR) was reduced to 0.10 Ω cm2 by using a Nafion®NRE 211 separator, providing a power density of over 100 kW kg−1 at 5 W h kg−1, calculated for discharge from 1.0 to 0.5 V. The maximum energy density was 21.8 W h kg−1 (31.2 W h kg−1 for discharge to 0 V). Both the ESR and electrode ionic resistance increased exponentially with decreasing temperature, while the specific capacitance decreased linearly from 770 F g−1 at 40 °C to 690 F g−1 at −40 °C. At −40 °C the energy loss at 500 W kg−1 was 15% relative to +25 °C.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.182
Threshold uncertainty score0.829

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.002
Scholarly communication0.0000.001
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.004
GPT teacher head0.160
Teacher spread0.156 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations59
Published2008
Admission routes1
Has abstractyes

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