Design and Photonic Properties of Novel Fluorinated Copolymers Bearing Phthalocyanine Side Groups
Bibliographic record
Abstract
Abstract The design and characterization of amorphous alternating copolymers endowed with a satisfactory thermal stability are reported. These alternating poly(CTFE‐ alt ‐CEVE) copolymers are synthesized by radical copolymerization of chlorotrifluoroethylene (CTFE) with 2‐chloroethyl vinyl ether (CEVE), which are first modified into poly[CTFE‐ alt ‐(2‐iodoethyl vinyl ether)] copolymers and then azidated in high yields. Alkynyl CF 3 ‐containing phthalocyanines (Pcs) are then grafted via a copper‐catalyzed Huisgen dipolar 1,3‐addition (“grafting onto”), hence providing fluorinated copolymers with different degrees of grafting (from 10 to 72%) of Pc dangling groups. Electronic spectral (absorption, excitation, and fluorescence) and photophysical properties (fluorescence lifetimes, τ F , and quantum yields, Φ F ) are evaluated.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".