Post-crystallization increases in the mechanical strength of self-assembled fibrillar networks is due to an increase in network supramolecular ordering
Bibliographic record
Abstract
Fibre–fibre interactions strongly influence the elastic properties of an organogel and are of critical importance to the ability of the network to entrain liquid oil. At 30 °C, there was a significant decrease in the storage modulus in time due to a decrease in the amount of crystalline material (i.e. a decrease in the free induction decay (FID) amplitude) and order of crystalline material (i.e. an increase in the FID T2 relaxation time (i.e. a measure of proton mobility)). Conversely, at 5 °C, there was an increase in G' in time but no changes were observed in both the amount of crystalline material and its order. This increase in G' was accompanied by a significant increase in the enthalpy of melt and the melting temperature, which translated to a significant increase in the entropy of melt of the system. This decrease in the absolute entropy of the system in time probably arose due to an increase in the number of van der Waals interactions between 12-hydroxystearic acid fibres. Hence the increased order of the system is due to the fibre–fibre interactions which results in a significant increase in G' in time at 5 °C.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.001 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".