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Record W2083999664 · doi:10.1021/ef0496707

Settling Properties of Asphaltene Aggregates

2005· article· en· W2083999664 on OpenAlexaff
Nazmul H.G. Rahmani, Tadeusz Dąbroś, Jacob H. Masliyah

Bibliographic record

VenueEnergy & Fuels · 2005
Typearticle
Languageen
FieldChemistry
TopicPetroleum Processing and Analysis
Canadian institutionsUniversity of Alberta
Fundersnot available
KeywordsSettlingFractal dimensionPorosityMaterials scienceMineralogyStokes flowFractalParticle sizeAggregate (composite)MechanicsFlow (mathematics)GeologyComposite materialThermodynamicsPhysicsMathematics

Abstract

fetched live from OpenAlex

Stokes law is the fundamental equation to describe the settling velocity of a particle for small Reynolds number flow and is applicable when the particle is spherical and impermeable. However, this equation is not suitable to describe the settling of porous aggregates found in many industrial applications, because of the nonsphericity and flow through the pores of the aggregates. Free-settling tests were used in the present work to estimate asphaltene aggregates porosity and effective density. The settling velocities of individual asphaltene aggregates are measured in a quiescent column via a photographic technique. Data analysis was conducted with a video frame grabber and digital imaging software, to determine the particle size, shape, and settling velocity. Results show that the aggregate size (area-equivalent diameter) determined from the video images ranged from 20 μm to 200 μm and the measured settling velocities varied from 100 μm/s to 564 μm/s. Settling velocity measurements indicated an inverse relationship between aggregate size and density. The reduced aggregate density with increasing size was attributed to the entrainment of fluid into the aggregate structure. These porous aggregates further collided with each other to form increasingly more-porous structures. An analysis was performed to understand the importance of aggregate fractal structure and its effective density on the settling velocity. The size-density fractal dimension of the asphaltene aggregates was estimated to be in the range of D 3 = 1.3−2.0. These relatively low fractal dimensions suggest that the asphaltene aggregates are highly porous and very tenuous.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.104
Threshold uncertainty score0.387

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.013
GPT teacher head0.215
Teacher spread0.202 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations28
Published2005
Admission routes1
Has abstractyes

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